| Core | Supplement |
|---|---|
| 1 Compare the general physical properties of metals and non-metals, including: (a) thermal conductivity (b) electrical conductivity (c) malleability and ductility (d) melting points and boiling points | |
| 2 Describe the general chemical properties of metals, limited to their reactions with: (a) dilute acids (b) cold water and steam (c) oxygen |
金属
IGCSE 化学 · 第 9 主题
9.1
金属的性质
大纲
来源:剑桥国际大纲
Physical properties
金属(metals)和非金属(non-metals)表现得非常不同:
| 性质 | 金属 | 非金属 |
|---|---|---|
| 导热性(thermal conductivity,导热) | 好 | 差 |
| 导电性(electrical conductivity) | 好 | 差(石墨除外) |
| 展性(malleability)和延性(ductility) | 有展性和延性 | 易碎(brittle,它们折断) |
| 熔点(melting point)和沸点(boiling point) | 通常高 | 通常低 |
Chemical properties
金属以三种主要方式反应:
- 与稀酸(acids)→ 一个盐(salt)+ 氢气(hydrogen)
- 与冷水或蒸汽(steam)→ 一个金属氢氧化物(或氧化物)+ 氢气
- 与氧气(oxygen)→ 一个金属氧化物(oxide)

Metallic bonding
Positive ions sit in a sea of delocalised electrons — that is why metals conduct and bend. Push the layers and the bond holds.
Metal property lab
Link metal properties to the particle model.
| 英文 | 中文 | 拼音 |
|---|---|---|
| metals | 金属 | jīn shǔ |
| non-metals | 非金属 | fēi jīn shǔ |
| thermal conductivity | 导热性 | dǎo rè xìng |
| electrical conductivity | 导电性 | dǎo diàn xìng |
| malleability | 展性 | zhǎn xìng |
| ductility | 延性 | yán xìng |
| brittle | 易碎 | yì suì |
| melting point | 熔点 | róng diǎn |
| boiling point | 沸点 | fèi diǎn |
| acids | 酸 | suān |
| salt | 盐 | yán |
| hydrogen | 氢气 | qīng qì |
| steam | 蒸汽 | zhēng qì |
| oxygen | 氧气 | yǎng qì |
| oxide | 氧化物 | yǎng huà wù |
| copper | 铜 | tóng |
9.2
金属的用途
大纲
| Core | Supplement |
|---|---|
| 1 Describe the uses of metals in terms of their physical properties, including: (a) aluminium in the manufacture of aircraft because of its low density (b) aluminium in the manufacture of overhead electrical cables because of its low density and good electrical conductivity (c) aluminium in food containers because of its resistance to corrosion (d) copper in electrical wiring because of its good electrical conductivity and ductility |
来源:剑桥国际大纲
一种金属因为它的物理性质被选来做一件工作。
- 铝(aluminium)因为它低的密度(density,它轻)被用来制造飞机。
- 铝因为它低的密度和好的导电性被用于架空电缆。
- 铝因为它抵抗腐蚀(corrosion)被用于食物容器。
- 铜(copper)因为它好的导电性和它的延性(它能被拉成线)被用于电线。
Metal use lab
Choose the property that explains each metal use.
| 英文 | 中文 | 拼音 |
|---|---|---|
| density | 密度 | mì dù |
| corrosion | 腐蚀 | fǔ shí |
9.3
合金及其性质
大纲
| Core | Supplement |
|---|---|
| 1 Describe an alloy as a mixture of a metal with other elements, including: (a) brass as a mixture of copper and zinc (b) stainless steel as a mixture of iron and other elements such as chromium, nickel and carbon | |
| 2 State that alloys can be harder and stronger than the pure metals and are more useful | 5 Explain in terms of structure how alloys can be harder and stronger than the pure metals because the different sized atoms in alloys mean the layers can no longer slide over each other |
| 3 Describe the uses of alloys in terms of their physical properties, including stainless steel in cutlery because of its hardness and resistance to rusting | |
| 4 Identify representations of alloys from diagrams of structure |
来源:剑桥国际大纲
一个合金(alloy)是一种金属与一种或多种其他元素的一个混合物(mixture)。
- 黄铜(brass)是铜和锌(zinc)的一个混合物。
- 不锈钢(stainless steel)是铁(iron)与其他元素如铬(chromium)、镍(nickel)和碳(carbon)的一个混合物。
合金通常比纯金属更硬、更强,这使它们更有用。例如,不锈钢因为它硬且不生锈被用于餐具。
为什么合金更硬。 在一个纯金属中,原子(atoms)都是同样的大小,所以层(layers)能容易地互相滑过。在一个合金中,不同大小的原子阻止层滑动,所以合金更硬、更强。

Alloy property lab
See why mixing atoms changes metal properties.
| 英文 | 中文 | 拼音 |
|---|---|---|
| alloy | 合金 | hé jīn |
| mixture | 混合物 | hùn hé wù |
| brass | 黄铜 | huáng tóng |
| zinc | 锌 | xīn |
| stainless steel | 不锈钢 | bù xiù gāng |
| iron | 铁 | tiě |
| chromium | 铬 | gè |
| nickel | 镍 | niè |
| carbon | 碳 | tàn |
| atoms | 原子 | yuán zi |
| layers | 层 | céng |
9.4
金属活动性顺序
大纲
| Core | Supplement |
|---|---|
| 1 State the order of the reactivity series as: potassium, sodium, calcium, magnesium, aluminium, carbon, zinc, iron, hydrogen, copper, silver, gold | 4 Describe the relative reactivities of metals in terms of their tendency to form positive ions, by displacement reactions, if any, with the aqueous ions of magnesium, zinc, iron, copper and silver |
| 2 Describe the reactions, if any, of: (a) potassium, sodium and calcium with cold water (b) magnesium with steam (c) magnesium, zinc, iron, copper, silver and gold with dilute hydrochloric acid and explain these reactions in terms of the position of the metals in the reactivity series | |
| 5 Explain the apparent unreactivity of aluminium in terms of its oxide layer | |
| 3 Deduce an order of reactivity from a given set of experimental results |
来源:剑桥国际大纲
金属活动性顺序(reactivity series)按金属有多活泼的顺序列出它们。碳和氢被包括以供比较:
钾(potassium)、钠(sodium)、钙(calcium)、镁(magnesium)、铝、碳、锌、铁、氢、铜、银、金
(最活泼在顶部,最不活泼在底部)

一种金属越高,它越容易构成正离子(ions)。这解释它的反应:
- 钾、钠和钙与冷水反应。
- 镁与蒸汽反应(但只非常缓慢地与冷水)。
- 镁、锌和铁与稀盐酸反应;铜、银和金不反应。
Displacement reactions
一种更活泼的金属会从一种较不活泼金属离子的溶液中置换它(一个置换反应(displacement reaction))。例如,锌从硫酸铜(II)溶液中置换铜,因为锌比铜更活泼:
要能说出你会看到什么,因为那是单独的分点:
- 溶液的蓝色变淡 —— 蓝色的 $\text{Cu}^{2+}$ 离子正在被消耗(硫酸锌是无色的)。
- 锌上覆盖了一层粉棕色固体 —— 那就是被置换出来的铜。
- 灰色的锌溶解并变小。
- 混合物变热 —— 置换反应放热。
金属与酸的反应有它自己的清单:泡腾(effervescence,逸出的氢气)以及固体溶解。如果是氧化铜(II)或碳酸铜与酸反应,还要加上溶液变蓝。绝不要把"放出氢气"当作观察现象 —— 你看不见这种气体,只能看见气泡,所以要写泡腾。
例题。 锌和铝都以氧化物的形式存在。哪一个能用碳加热提取?为什么?找出每种金属相对于碳在金属活动性顺序中的位置。锌在碳之下,所以碳是两者中更活泼的,能把氧从它那里夺走:氧化锌可以用碳加热还原。铝在碳之上,所以碳的活泼性不足以置换它,铝必须改用电解提取 - 这就是铝的提取成本高得多的原因。决定方法的那条线是碳所在的位置,而不是这个顺序表的顶端。
The special case of aluminium
铝看起来比它的位置所暗示的不那么活泼。这是因为它被一个薄的、强的氧化层(oxide layer)覆盖,它阻止其他物质到达下面的金属。
Displacement and the reactivity series
Step through a displacement. A more reactive metal pushes a less reactive one out of its compound — which is exactly what the reactivity series predicts.
| 英文 | 中文 | 拼音 |
|---|---|---|
| aluminium | 铝 | lǚ |
| reactivity series | 金属活动性顺序 | jīn shǔ huó dòng xìng shùn xù |
| potassium | 钾 | jiǎ |
| sodium | 钠 | nà |
| calcium | 钙 | gài |
| magnesium | 镁 | měi |
| ions | 离子 | lí zi |
| displacement reaction | 置换反应 | zhì huàn fǎn yìng |
| oxide layer | 氧化层 | yǎng huà céng |
| effervescence | 泡腾 | pào téng |
9.5
金属的腐蚀
大纲
| Core | Supplement |
|---|---|
| 1 State the conditions required for the rusting of iron and steel to form hydrated iron(III) oxide | |
| 2 State some common barrier methods, including painting, greasing and coating with plastic | 4 Describe the use of zinc in galvanising as an example of a barrier method and sacrificial protection |
| 3 Describe how barrier methods prevent rusting by excluding oxygen or water | 5 Explain sacrificial protection in terms of the reactivity series and in terms of electron loss |
来源:剑桥国际大纲

生锈(rusting)是铁和钢的腐蚀。生锈需要两样东西:氧气(从空气)和水。构成的铁锈(rust)是水合氧化铁(III)。


Stopping rust
隔离法(barrier methods)把氧气和水挡在离铁远处:
- 涂漆、涂油(用油覆盖),以及用塑料涂层。
镀锌(galvanising)意味着用一层锌涂层铁。这以两种方式起作用:
- 它是一个屏障(锌挡住空气和水);
- 它给牺牲保护(sacrificial protection)。因为锌比铁更活泼,锌失去电子(electrons)并代替铁腐蚀——即使表面被划伤。

Why iron rusts — and how to stop it
Step through rusting. Iron needs BOTH water and oxygen, and once it starts the rust flakes off to expose fresh metal — which is why we protect iron.
| 英文 | 中文 | 拼音 |
|---|---|---|
| rusting | 生锈 | shēng xiù |
| rust | 铁锈 | tiě xiù |
| barrier methods | 隔离法 | gé lí fǎ |
| galvanising | 镀锌 | dù xīn |
| sacrificial protection | 牺牲保护 | xī shēng bǎo hù |
| electrons | 电子 | diàn zi |
9.6
金属的提取
大纲
| Core | Supplement |
|---|---|
| 1 Describe the ease in obtaining metals from their ores, related to the position of the metal in the reactivity series | |
| 2 Describe the extraction of iron from hematite in the blast furnace, limited to: (a) the burning of carbon (coke) to provide heat and produce carbon dioxide (b) the reduction of carbon dioxide to carbon monoxide (c) the reduction of iron(III) oxide by carbon monoxide (d) the thermal decomposition of calcium carbonate/limestone to produce calcium oxide (e) the formation of slag Symbol equations are not required | 4 State the symbol equations for the extraction of iron from hematite (a) $\text{C} + \text{O}_2 \rightarrow \text{CO}_2$ (b) $\text{C} + \text{CO}_2 \rightarrow 2\text{CO}$ (c) $\text{Fe}_2\text{O}_3 + 3\text{CO} \rightarrow 2\text{Fe} + 3\text{CO}_2$ (d) $\text{CaCO}_3 \rightarrow \text{CaO} + \text{CO}_2$ (e) $\text{CaO} + \text{SiO}_2 \rightarrow \text{CaSiO}_3$ |
| 3 State that the main ore of aluminium is bauxite and that aluminium is extracted by electrolysis | 5 Describe the extraction of aluminium from purified bauxite/aluminium oxide, including: (a) the role of cryolite (b) why the carbon anodes need to be regularly replaced (c) the reactions at the electrodes, including ionic half-equations Details of the purification of bauxite are not required |
来源:剑桥国际大纲
一种金属如何从它的矿石(ore)中取出取决于它在金属活动性顺序中的位置。碳之下的金属能通过与碳加热(它移除氧)提取。碳之上的金属对这个太活泼,必须通过电解(electrolysis)提取。

Iron from the blast furnace
铁在一个高炉(blast furnace)中从它的矿石赤铁矿(hematite,氧化铁(III))提取:
- 碳(焦炭)在热空气中燃烧以给出二氧化碳和大量的热。
- 这个二氧化碳(carbon dioxide)与更多的碳反应以构成一氧化碳(carbon monoxide)。
- 一氧化碳把氧化铁(III)还原成铁(这是还原(reduction))。
- 石灰石(limestone,碳酸钙)在热中分解以构成氧化钙(calcium oxide)。
- 氧化钙与沙质杂质反应以构成炉渣(slag),它被移除。

Aluminium by electrolysis
铝通过电解从它的矿石铝土矿(bauxite,提纯成氧化铝)提取:
- 氧化铝被溶解在熔融的冰晶石(cryolite)中以降低它的熔点并节省能量。
- 在阴极(cathode),铝离子获得电子以构成铝金属。
- 在阳极(anode),氧气被构成。这个氧气与热的碳阳极反应并把它们烧掉,所以它们必须被定期替换。
Extracting iron in the blast furnace
Iron is below carbon in reactivity, so carbon can reduce its ore to the metal.
| 英文 | 中文 | 拼音 |
|---|---|---|
| ore | 矿石 | kuàng shí |
| electrolysis | 电解 | diàn jiě |
| hematite | 赤铁矿 | chì tiě kuàng |
| blast furnace | 高炉 | gāo lú |
| carbon dioxide | 二氧化碳 | èr yǎng huà tàn |
| carbon monoxide | 一氧化碳 | yī yǎng huà tàn |
| reduction | 还原 | huán yuán |
| limestone | 石灰石 | shí huī shí |
| calcium oxide | 氧化钙 | yǎng huà gài |
| slag | 炉渣 | lú zhā |
| bauxite | 铝土矿 | lǚ tǔ kuàng |
| cryolite | 冰晶石 | bīng jīng shí |
| cathode | 阴极 | yīn jí |
| anode | 阳极 | yáng jí |
9.6
考试技巧
- 学习金属活动性顺序(钾 → 金)。一种更活泼的金属从一种它离子的溶液中置换一种较不活泼的。
- 碳之上的金属通过电解提取;碳之下的(如铁)能通过与碳加热提取。
- 生锈需要水和氧气两者。隔离法(漆、油)把它们挡在外面;镀锌也给牺牲保护,因为更活泼的锌代替铁腐蚀。
- 合金比纯金属更硬,因为不同大小的原子阻止离子的层互相滑过。
本主题的互动课程
逐步学习,并即时检测练习。