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Using resources

AQA · GCSE · Chemistry · Topic 10

10.1

Using resources: sustainable chemistry

  • Resources are used, reused and recycled; potable water 饮用水 — filtered and sterilised fresh water, or desalinated sea water — is the first essential.
  • Life cycle assessment 生命周期评估s weigh a product's environmental cost stage by stage; reduce–reuse–recycle cuts every stage.
  • (Chem) corrosion 腐蚀 prevention, alloys, ceramics/polymers/composite 复合材料s, and the Haber process 哈伯法's compromise chemistry.
Vocabulary Train
English
potable water/ˈpəʊtəbl ˈwɔːtə/
life cycle assessment/laɪf ˈsaɪkl əˈsesmənt/
corrosion/kəˈrəʊʒn/
composite/ˈkɒmpəzɪt/
Haber process/ˈheɪbə ˈprəʊses/
10.1

Resources and potable water (4.10.1)

Syllabus

Resources and potable water (AQA 8462 statements 4.10.1.1-4.10.1.4).

  1. Distinguish finite from renewable resources and define sustainable development.
  2. Distinguish potable from pure water and describe UK treatment; compare with desalination.
  3. Describe sewage treatment in order, and compare ease of obtaining potable water from waste, ground and salt water.
  4. (HT) Describe phytomining and bioleaching for low-grade copper ores.

Source: Cambridge International syllabus

Humans use the Earth's resources for warmth, shelter, food and transport; finite resources (ores, fossil fuels) are processed for energy and materials; renewable ones replenish. Sustainable development 可持续发展 meets present needs without compromising future generations.

Potable water — safe to drink: low dissolved salts and microbes — but not pure water (it contains dissolved substances). Making potable water: source, filter beds, sterilisation — with the energy-hungry desalination 海水淡化 alternative.

In the UK, fresh rainwater is made potable by: choosing a source → filter beds → sterilising (with chlorine, ozone or UV light). Where fresh water is scarce, desalination — distillation or reverse osmosis — needs large amounts of energy.

Waste water (sewage) treatment: screening and grit removal → sedimentation (sewage sludge + effluent) → anaerobic digestion of the sludge → aerobic biological treatment of the effluent. Potable water is easiest from ground water, harder from waste, hardest (energy-wise) from salt water.

(HT) Alternative metal extraction — copper ores are scarce: phytomining (plants absorb metal compounds; harvest, burn to ash, extract) and bioleaching (bacteria produce leachate solutions of the metal compounds) avoid moving huge amounts of rock.

Vocabulary Train
English
desalination/dɪˌsælɪˈneɪʃn/
sustainable development/səˈsteɪnəbl dɪˈveləpmənt/
10.2

Life cycle assessment and recycling (4.10.2)

Syllabus

Life cycle assessment and recycling (AQA 8462 statements 4.10.2.1-4.10.2.2).

  1. List the four LCA stages and explain why LCAs are not purely objective.
  2. Evaluate reduce, reuse and recycling for given materials, with reasons.

Source: Cambridge International syllabus

LCA stages: extracting and processing raw materials; manufacturing and packaging; use and operation; disposal — including transport at each stage. Energy, water, resource use and waste are quantifiable; pollutant effects need value judgements — so LCAs are not purely objective, and selective LCAs can be misused (advertising). Compare plastic vs paper shopping bags.

Reduce, reuse, recycle: metals, glass, building materials, clay ceramics and most plastics come from limited raw materials; recycling cuts mining/quarrying impact and energy — e.g. glass crushed and remelted; scrap steel added to the blast furnace reduces iron-ore extraction. Some products (glass bottles) are reused; others recycled into different products; separation effort depends on the final product's requirements.

10.3

Using materials — chemistry only (4.10.3)

Syllabus

Using materials, chemistry only (AQA 8462 statements 4.10.3.1-4.10.3.2).

  1. Describe corrosion and its prevention, including sacrificial zinc.
  2. Recall named alloys with compositions and uses, and interpret alloy data.
  3. Compare glasses, clay ceramics, polymers and composites, including thermosoftening vs thermosetting.

Source: Cambridge International syllabus

Corrosion — destruction of materials by chemical reaction with the environment (e.g. iron + oxygen + water → rust). Prevention: greasing, painting, coating (galvanising with zinc, which gives sacrificial protection 牺牲保护 — it corrodes in place of the iron even when scratched) and alloying (stainless steel). Aluminium resists corrosion by its own protective oxide layer.

Alloys: bronze (copper + tin), brass (copper + zinc); gold jewellery alloyed with silver/copper/zinc — purity in carats (24 = 100 %; 18 = 75 %). Steels — iron + carbon (+ metals): high-carbon steel strong but brittle; low-carbon steel softer, shaped easily; stainless steel (Cr, Ni) hard and corrosion-resistant; aluminium alloys low density (aircraft).

Ceramics, polymers, composites: soda-lime glass (sand + sodium carbonate + limestone), borosilicate glass (sand + boron trioxide — higher melting point); clay ceramics (pottery, bricks — shaped wet clay, then fired). Polymers depend on monomers and conditions — LD and HD poly(ethene) both from ethene. Thermosoftening polymers melt on heating (recyclable chains); thermosetting polymer 热固性聚合物 does not (cross-links). Composites — a matrix/binder surrounding a reinforcement (fibres/fragments); know examples (fibreglass, concrete, carbon-fibre).

Vocabulary Train
English
sacrificial protection/ˌsækrɪˈfɪʃl prəˈtekʃn/
thermosetting polymer/ˈθɜːməsɪtɪŋ ˈpɒlɪmə/
10.4

The Haber process and NPK fertilisers — chemistry only (4.10.4)

Syllabus

The Haber process and NPK fertilisers, chemistry only (AQA 8462 statements 4.10.4.1-4.10.4.2).

  1. State the raw material sources and conditions of the Haber process.
  2. Describe the separation and recycling of ammonia and unreacted gases.
  3. (HT) Apply equilibrium principles to explain the compromise conditions.
  4. Name the NPK compounds and how they are produced, evaluating fertiliser manufacture.

Source: Cambridge International syllabus

The Haber process loop: gases over an iron catalyst, ammonia liquefied out, unreacted gases recycled.

Haber process: N₂ + 3 H₂ ⇌ 2 NH₃ — nitrogen from air, hydrogen from natural gas (methane + steam) [or electrolysis of water]. Conditions: iron catalyst, ~450 °C, ~200 atmospheres; the reaction is reversible — cool the mixture, the ammonia liquefies and is removed; unreacted N₂/H₂ are recycled.

(HT) Higher pressure favours ammonia (fewer gas molecules) but is expensive and unsafe; lower temperature favours the exothermic forward reaction but is slow — so the chosen conditions are a compromise between rate, yield and cost. Apply Le Chatelier to each condition change.

NPK fertilisers — formulations of nitrogen, phosphorus and potassium compounds for plant growth: ammonia → nitric acid (Ostwald); ammonia + nitric acid → ammonium nitrate; potassium chloride/potassium sulfate mined; phosphate rock treated with acid to make superphosphate. Evaluate the industrial production of fertilisers given data (raw materials, energy costs, % yield — e.g. the lab vs industrial ammonium sulfate routes).

10.4

Checklist before you call this topic done

  • Potable vs pure; the UK treatment sequence; desalination and its cost; sewage-treatment steps in order.
  • (HT) phytomining and bioleaching described end to end.
  • LCA four stages with the objectivity caveat; reduce-reuse-recycle examples with reasons.
  • (Chem) corrosion prevention incl. sacrificial zinc; named alloys with compositions; thermosoftening vs thermosetting; matrix + reinforcement.
  • (Chem/HT) Haber conditions with the compromise explained by equilibrium; the NPK compounds and their origins.

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